nigel.stanger / Digital_Repository
Transfer to URL with SHA Find file
Newer
Older
Digital_Repository / Misc / Mass downloads / UTas / 2848.html
Nigel Stanger on 7 May 2013 25 KB - Imported Misc directory.
Raw Blame History 
  1. <!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN"
  2. "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd">
  3. <html>
  4.   <head>
  5.     <title>UTas ePrints - Synthesis of Ketones and Methanols Containing Pyridinyl and N-Methylimidazolyl Groups</title>
  6.     <script type="text/javascript" src="http://eprints.utas.edu.au/javascript/auto.js"><!-- padder --></script>
  7.     <style type="text/css" media="screen">@import url(http://eprints.utas.edu.au/style/auto.css);</style>
  8.     <style type="text/css" media="print">@import url(http://eprints.utas.edu.au/style/print.css);</style>
  9.     <link rel="icon" href="/images/eprints/favicon.ico" type="image/x-icon" />
  10.     <link rel="shortcut icon" href="/images/eprints/favicon.ico" type="image/x-icon" />
  11.     <link rel="Top" href="http://eprints.utas.edu.au/" />
  12.     <link rel="Search" href="http://eprints.utas.edu.au/cgi/search" />
  13.     <meta content="Canty, A.J." name="eprints.creators_name" />
  14. <meta content="George, E.E." name="eprints.creators_name" />
  15. <meta content="Lee, C.V." name="eprints.creators_name" />
  16. <meta content="allan.canty@utas.edu.au" name="eprints.creators_id" />
  17. <meta content="" name="eprints.creators_id" />
  18. <meta content="" name="eprints.creators_id" />
  19. <meta content="article" name="eprints.type" />
  20. <meta content="2008-01-11 04:32:28" name="eprints.datestamp" />
  21. <meta content="2008-01-11 04:32:28" name="eprints.lastmod" />
  22. <meta content="show" name="eprints.metadata_visibility" />
  23. <meta content="Synthesis of Ketones and Methanols Containing
  24. Pyridinyl and N-Methylimidazolyl Groups" name="eprints.title" />
  25. <meta content="pub" name="eprints.ispublished" />
  26. <meta content="250300" name="eprints.subjects" />
  27. <meta content="restricted" name="eprints.full_text_status" />
  28. <meta content="N-Methylimidazolyllithium reacts with N-methylimidazole-2-carbaldehyde to form bis(N-methylimidazol-2-yl)methanol, and with the esters ethyl N-methylimidazole-2-carboxylate and ethyl pyridine-2-carboxylate to give bis(N-methylimidazol-2-yl)methanone, (mim)2CO, and (N-methylimidazol-2-yl)(pyridin-2-yl)methanone, (Py)(mim)CO, respectively. The ketones react with
  29. N-methylimidazolyllithium to give tris(N-methylimidazol-2-yl)methanol,(mim)3COH, and bis(N-methylimidazol-
  30. 2-yl)(pyridin-2-y1)methanol(Py)(mim)2COH, respectively." name="eprints.abstract" />
  31. <meta content="1983" name="eprints.date" />
  32. <meta content="published" name="eprints.date_type" />
  33. <meta content="Australian Journal of Chemistry" name="eprints.publication" />
  34. <meta content="36" name="eprints.volume" />
  35. <meta content="2" name="eprints.number" />
  36. <meta content="415-418" name="eprints.pagerange" />
  37. <meta content="10.1071/CH9830415" name="eprints.id_number" />
  38. <meta content="TRUE" name="eprints.refereed" />
  39. <meta content="0004-9425" name="eprints.issn" />
  40. <meta content="http://www.publish.csiro.au/nid/51/paper/CH9830415.htm" name="eprints.official_url" />
  41. <meta content="
  42.  
  43. (1) (a) University of Tasmania. (b) University of Western Australia.
  44. (2) Pope, W. J.; Peachey, S. J. h o c . Chem. Soc., London 1907,23,86;
  45. J. Chem. Soc. 1909. 571.
  46. (3) Uson, R.; Fornies, J.; Navarro, R. J. Organomet. Chem. 1975,96,
  47. (4) Stille, J. K.; Lau, K. S. Y. J. Am. Chem. SOC. 1976, 98, 5841.
  48. (5) Milstein, D.; Stille, J. K. J. Am. Chem. SOC. 1979, 101, 4981.
  49. 307; Synth. React. Inorg. Met.-Org. Chem. 1977, 7, 235.
  50. (6) Milstein, D.; Stille, J. K. J. Am. Chem. SOC. 1979, 101, 4992.
  51. (7) Gillie, A.; Stille, J. K. J. Am. Chem. SOC. 1980, 102, 4933.
  52. (8) h a r , M. K.; Stille, J. K. J. Am. Chem. SOC. 1981, 103, 4174.
  53. (9) Moravskiy, A.; Stille, J. K. J. Am. Chem. SOC. 1981, 103, 4182.
  54. (10) For a recent review, see: Stille, J. K. In The Chemistry of the
  55. Metal-Carbon Bond; Hartley, F. R., Patai, S., Eds.; Wiley: New York,
  56. 1985; Vol. 2, p 625.
  57. (11) Weinberg, E. L.; Hunter, B. K.; Baird, M. C. J. Organomet. Chem.
  58. 1982, 240, 95.
  59.  
  60. (12) (a) Ryabov, A. D.; Eliseev, A. V.; Yateimirsky, A. K. Appl. Organomet.
  61. Chem. 1988, 2, 19. (b) Kurosawa, H.; Emoto, M.; Kawasaki,
  62. Y. J. Organomet. Chem. 1988, 346, 137.
  63. (13) Catellani, M.; Chiusoli, G. P. J. Organomet. Chem. 1988,346, C27.
  64. Catellani, M.; Mann, B. E. J. Organomet. Chem. 1990,390, 251.
  65. (14) Diversi, P.; Fasce, D.; Santini, R. J. Organomet. Chem. 1984,269,
  66. 285.
  67. (15) (a) Maassarani, F.; Pfeffer, M.; Le Borgne, G.; Jastrzebski, J. T.
  68. B. H.; van Koten, G. Organometallics 1987, 6, 1111. (b) Cornioley-
  69. Deuschel, C.; von Zelewsky, A. Inorg. Chem. 1987,26, 3354.
  70. (16) Byers, P. K.; Canty, A. J.; Skelton, B. W.; White, A. H. J. Chem.
  71. SOC.,C hem. Commun. 1986, 1722.
  72. (17) Byers, P. K.; Canty, A. J.; Skelton, B. W.; White, A. H. Organometallics
  73. 1990, 9, 826.
  74. (18) Byers, P. K.; Canty, A. J.; Traill, P. R.; Watson, A. A. J. Organomet.
  75. Chem. 1990,390,399.
  76. (19) de Graaf, W.; Boersma, J.; Smeets, W. J. J.; Spek, A. L.; van
  77. Koten, G. Organometallics 1989, 8, 2907.
  78. (20) de Graaf, W.; Boersma, J.; van Koten, G. Organometallics 1990,
  79. 9, 1479.
  80. (21) Canty, A. J.; Watson, A. A.; Skelton, B. W.; White, A. H. J.
  81. Organomet. Chem. 1989, 367, C25.
  82. (22) Byers, P. K.; Canty, A. J.; Honeyman, R. T.; Watson, A. A. J.
  83. Organomet. Chem. 1990, 385, 429.
  84. (23) Albano, V. G.; Castellari, C.; Cucciolito, M. E.; Panunzi, A,; Vitagliano,
  85. A. Organometallics 1990, 9, 1269.
  86. (24) Canty, A. J.; Watson, A. A. Inorg. Chim. Acta 1988, 154, 5.
  87. (25) Byers, P. K.; Canty, A. J. J. Chem. SOC.C, hem. Commun. 1988,
  88.  
  89. (26) Aye, K.-T.; Canty, A. J.; Crespo, M.; Puddephatt, R. J.; Scott, J.
  90. (27) Byers, P. K.; Canty, A. J. Organometallics 1990, 9, 210.
  91. D.; Watson, A. A. Organometallics 1989,8, 1518.
  92.  
  93. (28) Clark, R. J. H.; Croud, V. 9.;D awes, H. M.; Hursthouse, M. 9.
  94. Polyhedron 1988, 24, 2611.
  95.  
  96. 9) Brown, D. G.; Byers, P. K.; Canty, A. J. Organometallics 1990,
  97. (30) Byers, P. K.; Canty, A. J.; Crespo, M.; Puddephatt, R. J.; Scott,
  98. (31) Monaghan, P. K.; Puddephatt, R. J. Organometallics 1985, 4,
  99. 9, 1231.
  100. J. D. Organometallics 1988, 7, 1363.
  101. 1- A M
  102. (32) Scott, J. D.; Crespo, M.; Anderson, C.; Puddephatt, R. J. Or-
  103. (33) Moneghan, P. K.; Puddephatt, R. J. J. Chem. SOC.D, alton Trans.
  104. ganometallics 1987, 6, 1772.
  105. 1988,595.
  106.  
  107. (34) See e.g.: Clegg, D. E.; Hall, J. R.; Swile, G. A. J. Orgonomet.
  108. (35) Crespo, M.; Puddephatt, R. J. Organometallics 1987, 6, 2548.
  109.  
  110. (36) Byers, P. K.; Canty, A. J.; Engelhardt, L. M.; White, A. H. J.
  111. (37) Perrin, D. D.; Armarego, W. L. F.; Perrin, 0. R. Purification of
  112. Chem. SOC., Dalton Trans. 1986, 1731.
  113. Laboratory Chemicals, 2nd ed.; Pergamon: Oxford, England, 1980.
  114.  
  115. (38) Ibere, J. A,, Hamilton, W. C., Eds. International Tables for XRay
  116. Crystallography; Kynoch Press: Birmingham, England, 1974; Vol.
  117. 4.
  118. 2.4; Universities of Western Australia and Maryland, 1988.
  119. (39) Hall, S. R., Stewart, J. M., Eds. XTAL User's Manual-" name="eprints.referencetext" />
  120. <meta content="Canty, A.J. and George, E.E. and Lee, C.V. (1983) Synthesis of Ketones and Methanols Containing Pyridinyl and N-Methylimidazolyl Groups. Australian Journal of Chemistry, 36 (2). pp. 415-418. ISSN 0004-9425" name="eprints.citation" />
  121. <meta content="http://eprints.utas.edu.au/2848/1/AJC1983_2C_415.pdf" name="eprints.document_url" />
  122. <link rel="schema.DC" href="http://purl.org/DC/elements/1.0/" />
  123. <meta content="Synthesis of Ketones and Methanols Containing
  124. Pyridinyl and N-Methylimidazolyl Groups" name="DC.title" />
  125. <meta content="Canty, A.J." name="DC.creator" />
  126. <meta content="George, E.E." name="DC.creator" />
  127. <meta content="Lee, C.V." name="DC.creator" />
  128. <meta content="250300 Organic Chemistry" name="DC.subject" />
  129. <meta content="N-Methylimidazolyllithium reacts with N-methylimidazole-2-carbaldehyde to form bis(N-methylimidazol-2-yl)methanol, and with the esters ethyl N-methylimidazole-2-carboxylate and ethyl pyridine-2-carboxylate to give bis(N-methylimidazol-2-yl)methanone, (mim)2CO, and (N-methylimidazol-2-yl)(pyridin-2-yl)methanone, (Py)(mim)CO, respectively. The ketones react with
  130. N-methylimidazolyllithium to give tris(N-methylimidazol-2-yl)methanol,(mim)3COH, and bis(N-methylimidazol-
  131. 2-yl)(pyridin-2-y1)methanol(Py)(mim)2COH, respectively." name="DC.description" />
  132. <meta content="1983" name="DC.date" />
  133. <meta content="Article" name="DC.type" />
  134. <meta content="PeerReviewed" name="DC.type" />
  135. <meta content="application/pdf" name="DC.format" />
  136. <meta content="http://eprints.utas.edu.au/2848/1/AJC1983_2C_415.pdf" name="DC.identifier" />
  137. <meta content="http://www.publish.csiro.au/nid/51/paper/CH9830415.htm" name="DC.relation" />
  138. <meta content="Canty, A.J. and George, E.E. and Lee, C.V. (1983) Synthesis of Ketones and Methanols Containing Pyridinyl and N-Methylimidazolyl Groups. Australian Journal of Chemistry, 36 (2). pp. 415-418. ISSN 0004-9425" name="DC.identifier" />
  139. <meta content="http://eprints.utas.edu.au/2848/" name="DC.relation" />
  140. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/BibTeX/epprod-eprint-2848.bib" title="BibTeX" type="text/plain" />
  141. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/ContextObject/epprod-eprint-2848.xml" title="OpenURL ContextObject" type="text/xml" />
  142. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/ContextObject::Dissertation/epprod-eprint-2848.xml" title="OpenURL Dissertation" type="text/xml" />
  143. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/ContextObject::Journal/epprod-eprint-2848.xml" title="OpenURL Journal" type="text/xml" />
  144. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/DC/epprod-eprint-2848.txt" title="Dublin Core" type="text/plain" />
  145. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/DIDL/epprod-eprint-2848.xml" title="DIDL" type="text/xml" />
  146. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/EndNote/epprod-eprint-2848.enw" title="EndNote" type="text/plain" />
  147. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/HTML/epprod-eprint-2848.html" title="HTML Citation" type="text/html; charset=utf-8" />
  148. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/METS/epprod-eprint-2848.xml" title="METS" type="text/xml" />
  149. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/MODS/epprod-eprint-2848.xml" title="MODS" type="text/xml" />
  150. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/RIS/epprod-eprint-2848.ris" title="Reference Manager" type="text/plain" />
  151. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/Refer/epprod-eprint-2848.refer" title="Refer" type="text/plain" />
  152. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/Simple/epprod-eprint-2848text" title="Simple Metadata" type="text/plain" />
  153. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/Text/epprod-eprint-2848.txt" title="ASCII Citation" type="text/plain; charset=utf-8" />
  154. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2848/XML/epprod-eprint-2848.xml" title="EP3 XML" type="text/xml" />
  155.  
  156.   </head>
  157.   <body bgcolor="#ffffff" text="#000000" onLoad="loadRoutine(); MM_preloadImages('images/eprints/ePrints_banner_r5_c5_f2.gif','images/eprints/ePrints_banner_r5_c7_f2.gif','images/eprints/ePrints_banner_r5_c8_f2.gif','images/eprints/ePrints_banner_r5_c9_f2.gif','images/eprints/ePrints_banner_r5_c10_f2.gif','images/eprints/ePrints_banner_r5_c11_f2.gif','images/eprints/ePrints_banner_r6_c4_f2.gif')">
  158.     
  159.     <div class="ep_noprint"><noscript><style type="text/css">@import url(http://eprints.utas.edu.au/style/nojs.css);</style></noscript></div>
  160.  
  161.  
  162.  
  163.  
  164. <table width="795" border="0" cellspacing="0" cellpadding="0">
  165.   <tr>
  166.     <td><script language="JavaScript1.2">mmLoadMenus();</script>
  167.       <table border="0" cellpadding="0" cellspacing="0" width="795">
  168.         <!-- fwtable fwsrc="eprints_banner_final2.png" fwbase="ePrints_banner.gif" fwstyle="Dreamweaver" fwdocid = "1249563342" fwnested="0" -->
  169.         <tr>
  170.           <td><img src="/images/eprints/spacer.gif" width="32" height="1" border="0" alt="" /></td>
  171.           <td><img src="/images/eprints/spacer.gif" width="104" height="1" border="0" alt="" /></td>
  172.           <td><img src="/images/eprints/spacer.gif" width="44" height="1" border="0" alt="" /></td>
  173.           <td><img src="/images/eprints/spacer.gif" width="105" height="1" border="0" alt="" /></td>
  174.           <td><img src="/images/eprints/spacer.gif" width="41" height="1" border="0" alt="" /></td>
  175.           <td><img src="/images/eprints/spacer.gif" width="16" height="1" border="0" alt="" /></td>
  176.           <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  177.           <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  178.           <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  179.           <td><img src="/images/eprints/spacer.gif" width="82" height="1" border="0" alt="" /></td>
  180.           <td><img src="/images/eprints/spacer.gif" width="69" height="1" border="0" alt="" /></td>
  181.           <td><img src="/images/eprints/spacer.gif" width="98" height="1" border="0" alt="" /></td>
  182.           <td><img src="/images/eprints/spacer.gif" width="1" height="1" border="0" alt="" /></td>
  183.         </tr>
  184.         <tr>
  185.           <td colspan="12"><img name="ePrints_banner_r1_c1" src="/images/eprints/ePrints_banner_r1_c1.gif" width="795" height="10" border="0" alt="" /></td>
  186.           <td><img src="/images/eprints/spacer.gif" width="1" height="10" border="0" alt="" /></td>
  187.         </tr>
  188.         <tr>
  189.           <td rowspan="6"><img name="ePrints_banner_r2_c1" src="/images/eprints/ePrints_banner_r2_c1.gif" width="32" height="118" border="0" alt="" /></td>
  190.           <td rowspan="5"><a href="http://www.utas.edu.au/"><img name="ePrints_banner_r2_c2" src="/images/eprints/ePrints_banner_r2_c2.gif" width="104" height="103" border="0" alt="" /></a></td>
  191.           <td colspan="10"><img name="ePrints_banner_r2_c3" src="/images/eprints/ePrints_banner_r2_c3.gif" width="659" height="41" border="0" alt="" /></td>
  192.           <td><img src="/images/eprints/spacer.gif" width="1" height="41" border="0" alt="" /></td>
  193.         </tr>
  194.         <tr>
  195.           <td colspan="3"><a href="http://eprints.utas.edu.au/"><img name="ePrints_banner_r3_c3" src="/images/eprints/ePrints_banner_r3_c3.gif" width="190" height="31" border="0" alt="" /></a></td>
  196.           <td rowspan="2" colspan="7"><img name="ePrints_banner_r3_c6" src="/images/eprints/ePrints_banner_r3_c6.gif" width="469" height="37" border="0" alt="" /></td>
  197.           <td><img src="/images/eprints/spacer.gif" width="1" height="31" border="0" alt="" /></td>
  198.         </tr>
  199.         <tr>
  200.           <td colspan="3"><img name="ePrints_banner_r4_c3" src="/images/eprints/ePrints_banner_r4_c3.gif" width="190" height="6" border="0" alt="" /></td>
  201.           <td><img src="/images/eprints/spacer.gif" width="1" height="6" border="0" alt="" /></td>
  202.         </tr>
  203.         <tr>
  204.           <td colspan="2"><img name="ePrints_banner_r5_c3" src="/images/eprints/ePrints_banner_r5_c3.gif" width="149" height="1" border="0" alt="" /></td>
  205.           <td rowspan="2" colspan="2"><a href="/information.html" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821132634_0,0,25,null,'ePrints_banner_r5_c5');MM_swapImage('ePrints_banner_r5_c5','','/images/eprints/ePrints_banner_r5_c5_f2.gif',1);"><img name="ePrints_banner_r5_c5" src="/images/eprints/ePrints_banner_r5_c5.gif" width="57" height="25" border="0" alt="About" /></a></td>
  206.           <td rowspan="2"><a href="/view/" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133021_1,0,25,null,'ePrints_banner_r5_c7');MM_swapImage('ePrints_banner_r5_c7','','/images/eprints/ePrints_banner_r5_c7_f2.gif',1);"><img name="ePrints_banner_r5_c7" src="/images/eprints/ePrints_banner_r5_c7.gif" width="68" height="25" border="0" alt="Browse" /></a></td>
  207.           <td rowspan="2"><a href="/perl/search/simple" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133201_2,0,25,null,'ePrints_banner_r5_c8');MM_swapImage('ePrints_banner_r5_c8','','/images/eprints/ePrints_banner_r5_c8_f2.gif',1);"><img name="ePrints_banner_r5_c8" src="/images/eprints/ePrints_banner_r5_c8.gif" width="68" height="25" border="0" alt="Search" /></a></td>
  208.           <td rowspan="2"><a href="/perl/register" onMouseOut="MM_swapImgRestore();MM_startTimeout();" onMouseOver="MM_showMenu(window.mm_menu_1018171924_3,0,25,null,'ePrints_banner_r5_c9');MM_swapImage('ePrints_banner_r5_c9','','/images/eprints/ePrints_banner_r5_c9_f2.gif',1);"><img name="ePrints_banner_r5_c9" src="/images/eprints/ePrints_banner_r5_c9.gif" width="68" height="25" border="0" alt="register" /></a></td>
  209.           <td rowspan="2"><a href="/perl/users/home" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133422_4,0,25,null,'ePrints_banner_r5_c10');MM_swapImage('ePrints_banner_r5_c10','','/images/eprints/ePrints_banner_r5_c10_f2.gif',1);"><img name="ePrints_banner_r5_c10" src="/images/eprints/ePrints_banner_r5_c10.gif" width="82" height="25" border="0" alt="user area" /></a></td>
  210.           <td rowspan="2"><a href="/help/" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133514_5,0,25,null,'ePrints_banner_r5_c11');MM_swapImage('ePrints_banner_r5_c11','','/images/eprints/ePrints_banner_r5_c11_f2.gif',1);"><img name="ePrints_banner_r5_c11" src="/images/eprints/ePrints_banner_r5_c11.gif" width="69" height="25" border="0" alt="Help" /></a></td>
  211.           <td rowspan="3" colspan="4"><img name="ePrints_banner_r5_c12" src="/images/eprints/ePrints_banner_r5_c12.gif" width="98" height="40" border="0" alt="" /></td>
  212.           <td><img src="/images/eprints/spacer.gif" width="1" height="1" border="0" alt="" /></td>
  213.         </tr>
  214.         <tr>
  215.           <td rowspan="2"><img name="ePrints_banner_r6_c3" src="/images/eprints/ePrints_banner_r6_c3.gif" width="44" height="39" border="0" alt="ePrints home" /></td>
  216.           <td><a href="/" onMouseOut="MM_swapImgRestore()" onMouseOver="MM_swapImage('ePrints_banner_r6_c4','','/images/eprints/ePrints_banner_r6_c4_f2.gif',1);"><img name="ePrints_banner_r6_c4" src="/images/eprints/ePrints_banner_r6_c4.gif" width="105" height="24" border="0" alt="ePrints home" /></a></td>
  217.           <td><img src="/images/eprints/spacer.gif" width="1" height="24" border="0" alt="" /></td>
  218.         </tr>
  219.         <tr>
  220.           <td><img name="ePrints_banner_r7_c2" src="/images/eprints/ePrints_banner_r7_c2.gif" width="104" height="15" border="0" alt="" /></td>
  221.           <td colspan="8"><img name="ePrints_banner_r7_c4" src="/images/eprints/ePrints_banner_r7_c4.gif" width="517" height="15" border="0" alt="" /></td>
  222.           <td><img src="/images/eprints/spacer.gif" width="1" height="15" border="0" alt="" /></td>
  223.         </tr>
  224.       </table></td>
  225.   </tr>
  226.     <tr><td><table width="100%" style="font-size: 90%; border: solid 1px #ccc; padding: 3px"><tr>
  227.       <td align="left"><a href="http://eprints.utas.edu.au/cgi/users/home">Login</a> | <a href="http://eprints.utas.edu.au/cgi/register">Create Account</a></td>
  228.       <td align="right" style="white-space: nowrap">
  229.         <form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/search" style="display:inline">
  230.           <input class="ep_tm_searchbarbox" size="20" type="text" name="q" />
  231.           <input class="ep_tm_searchbarbutton" value="Search" type="submit" name="_action_search" />
  232.           <input type="hidden" name="_order" value="bytitle" />
  233.           <input type="hidden" name="basic_srchtype" value="ALL" />
  234.           <input type="hidden" name="_satisfyall" value="ALL" />
  235.         </form>
  236.       </td>
  237.     </tr></table></td></tr>
  238.   <tr>
  239.     <td class="toplinks"><!-- InstanceBeginEditable name="content" -->
  240.  
  241.  
  242. <div align="center">
  243.   
  244.   <table width="720" class="ep_tm_main"><tr><td align="left">
  245.     <h1 class="ep_tm_pagetitle">Synthesis of Ketones and Methanols Containing Pyridinyl and N-Methylimidazolyl Groups</h1>
  246.     <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">George, E.E.</span> and <span class="person_name">Lee, C.V.</span> (1983) <xhtml:em>Synthesis of Ketones and Methanols Containing Pyridinyl and N-Methylimidazolyl Groups.</xhtml:em> Australian Journal of Chemistry, 36 (2). pp. 415-418. ISSN 0004-9425</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2848/1/AJC1983_2C_415.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2848/1/AJC1983_2C_415.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />196Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="4060" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://www.publish.csiro.au/nid/51/paper/CH9830415.htm">http://www.publish.csiro.au/nid/51/paper/CH9830415.htm</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">N-Methylimidazolyllithium reacts with N-methylimidazole-2-carbaldehyde to form bis(N-methylimidazol-2-yl)methanol, and with the esters ethyl N-methylimidazole-2-carboxylate and ethyl pyridine-2-carboxylate to give bis(N-methylimidazol-2-yl)methanone, (mim)2CO, and (N-methylimidazol-2-yl)(pyridin-2-yl)methanone, (Py)(mim)CO, respectively. The ketones react with&#13;
  247. N-methylimidazolyllithium to give tris(N-methylimidazol-2-yl)methanol,(mim)3COH, and bis(N-methylimidazol-&#13;
  248. 2-yl)(pyridin-2-y1)methanol(Py)(mim)2COH, respectively.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250300.html">250000 Chemical Sciences &gt; 250300 Organic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2848</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">11 Jan 2008 15:32</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">11 Jan 2008 15:32</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2848;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2848">item control page</a></p>
  249.   </td></tr></table>
  250. </div>
  251.  
  252.  
  253.  
  254.     <!-- InstanceEndEditable --></td>
  255.   </tr>
  256.   <tr>
  257.     <td><!-- #BeginLibraryItem "/Library/footer_eprints.lbi" -->
  258.     <table width="795" border="0" align="left" cellpadding="0" class="footer">
  259.   <tr valign="top">
  260. <td colspan="2"><div align="center"><a href="http://www.utas.edu.au">UTAS home</a> | <a href="http://www.utas.edu.au/library/">Library home</a> | <a href="/">ePrints home</a> | <a href="/contact.html">contact</a> | <a href="/information.html">about</a> | <a href="/view/">browse</a> | <a href="/perl/search/simple">search</a> | <a href="/perl/register">register</a> | <a href="/perl/users/home">user area</a> | <a href="/help/">help</a></div><br /></td>
  261. </tr>
  262. <tr><td colspan="2"><p><img src="/images/eprints/footerline.gif" width="100%" height="4" /></p></td></tr>
  263.       <tr valign="top">
  264.         <td width="68%" class="footer">Authorised by the University Librarian<br />
  265. © University of Tasmania ABN 30 764 374 782<br />
  266.       <a href="http://www.utas.edu.au/cricos/">CRICOS Provider Code 00586B</a> | <a href="http://www.utas.edu.au/copyright/copyright_disclaimers.html">Copyright &amp; Disclaimers</a> | <a href="http://www.utas.edu.au/accessibility/index.html">Accessibility</a> | <a href="http://eprints.utas.edu.au/feedback/">Site Feedback</a>  </td>
  267.         <td width="32%"><div align="right">
  268.             <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><img src="http://www.utas.edu.au/shared/logos/unioftasstrip.gif" alt="University of Tasmania Home Page" width="260" height="16" border="0" align="right" /></a></p>
  269.             <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><br />
  270.             </a></p>
  271.         </div></td>
  272.       </tr>
  273.       <tr valign="top">
  274.         <td><p>  </p></td>
  275.         <td><div align="right"><span class="NoPrint"><a href="http://www.eprints.org/software/"><img src="/images/eprintslogo.gif" alt="ePrints logo" width="77" height="29" border="0" align="bottom" /></a></span></div></td>
  276.       </tr>
  277.     </table>
  278.     <!-- #EndLibraryItem -->
  279.     <div align="center"></div></td>
  280.   </tr>
  281. </table>
  282.  
  283.   </body>
  284. </html>